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Hindered Csbnd N bond rotation in triazinyl dithiocarbamates. The substituent and solvent effects on the rotation around a Csbnd N amide bond were studied for a series of triazine dibenzylcarbamodithioates. Density functional theory DFT calculations reproduced the experimental observations with various substituents, Seattle hot spots well as solvents. From the detailed analysis of the DFTwe Massage envy north 10th street Richmond that the electron donating dibenzyl amine group increased the electron population on the triazinyl ring, which decreased the Flirchi dating Norwalk barrier of the Csbnd N bond in the dithiocarbamate group attached to the triazinyl ring. The higher electron population on the triazine moiety stabilizes the partial double bond character of the Ssbnd C bond, which competitively excludes the double bond character of the Csbnd N bond.

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